Titto Sunil John

Probing Hydrogen Activation in a Dimetal Dihydride Complex by Symmetric Exchange with Parahydrogen | Journal of the American Chemical Society @mpi_nat @UTSWMedCenter pubs.acs.org/doi/10.1021/ja…

It can be done!.....sometimes 😅Check out our latest work @ChemRxiv where @StasChem figured out how to make heterobimetallic complexes within symmetric dinucleating ligand environments. 🤩chemrxiv.org/doi/full/10.26…

The work of Marcella and Janine on the non-innocence of a bis(β-diketiminate) is now part of a Themed Issue dedicated to the 60th birthday of Christian Limberg and Franc Meyer. Thanks to @dfg_public and TU Chemnitz for funding!!! #CHEMnitz onlinelibrary.wiley.com/doi/10.1002/za…

Substrate-Dependent Hydridic and Radical Reactivity of Triiron Hydride Clusters dx.doi.org/10.1021/acs.in…

Mononitrosyl!! The missing link of Iron-Sulfur enzymes' nitrosylative degradation?? Pure synthetic bioinorganic chemistry by @Subhade31669641 and @ArijeetGhude. The latest publication of @multimetallics is now out in @J_A_C_S. #chemistry #FeSChemistry pubs.acs.org/doi/10.1021/ja…

Super excited to share my latest publication with @multimetallics group. 😁😁 Always in awe of how an unexpected result ends up being a missing piece in an age-old puzzle. 🔍🔍 We thought we knew how CO bound to an Iron surface. But did we? Read on: pubs.acs.org/doi/full/10.10…

Read about how our tricobalt platform can support a stable carbide! Characterized via single-crystal XRD and carbon NMR. Congratulations to our graduate student Nick on a job well done! pubs.acs.org/doi/10.1021/ja…

Happy to share our latest Caltech/MPI-CEC collab from my PhD coauthored with another @ColgateChem alum Mike He. We reported the synthesis and spectroscopy of the first FeS cluster with a bridging carbide pubs.acs.org/doi/10.1021/ja…

Congratulations to @Jesse_Gordon9 ! We're so proud and excited of our undergraduate research alumnus as he starts as an Assistant Professor at Northwestern University!

Probing substrate binding inside a paramagnetic cavity: a NMR spectroscopy toolbox for combined experimental and theoretical investigation - Chemical Science (RSC Publishing) by SP Rath doi.org/10.1039/D4SC05…

As the subject of this Postdoctoral Researcher in the Spotlight, Juan Felipe Torres Gonzalez of the @DincaGroup reveals the things he’d do if he didn’t have to sleep, three of his favorite fictional characters, small things that improve his day, and more! chemistry.mit.edu/chemistry-news…

An enzyme that can synthesize aromatic azides! Bioorthogonal no more? 😝 Cool paper in @NatureChemistry by Wenjun Zhang & colleagues @UCB_Chemistry nature.com/articles/s4155…

[Great News🎉] Thrilled to announce that our latest paper "Direct evidence for a carbon–carbon one-electron σ-bond" is now out in @nature ! Huge congrats to Takuya @Tky_SMJR , Soki @SokiKAWAGUCHI , and all involved🎉🎊 nature.com/articles/s4158…

Photocatalytic Decarboxylative Alkylation of Cyclic Imine–BF3 Complexes: A Modular Route to Functionalized Azacycles | Journal of the American Chemical Society @UFChemistry #Photocatalysis #Decarboxylative #Alkylation #Imine #Azacycles @TotalSyntheses pubs.acs.org/doi/10.1021/ja…

At long last, we have relatively definitive local oxidation states in iron #nitrosyl complexes (the method should apply to other transition metals as well)! NO Oxidation States in #Nonheme Iron Nitrosyls: A DMRG-CASSCF Study of {FeNO}6 –10 Complexes chemrxiv.org/engage/chemrxi…

More than 4 years in the making, and our 1st Monash/Bath (with Mike Hill) study is out on ChemRxiv. A full series of heavier Gp 2 metal hydride complexes [(Nacnac)M(mu-H)]2 (M=Mg, Ca, Sr or Ba). great work by Dom, Matt and Dafydd. #ozchem @ChemistryMonash tinyurl.com/4sm9vaxa

Happy to have this paper see the light of day and featured as the TOC of the week! Check out this cool reactivity below ⤵️

TIL Chem Rev pays YOU when you publish a review. I hope PIs have been sharing that honorarium with their trainees.

Ocampo and Murray report the ligand reactivity of anionic tris (β-diketiminate) copper complexes toward alkyl halides and Brønsted acids. Please enjoy our #TOCoftheWeek: pubs.acs.org/doi/10.1021/ac…

One last job. #YusufDikec