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🔋 What if an electrolyte salt could become the energy-storing material?
In our new article, we show how lithium perchlorate (LiClO₄) can undergo an 8-electron reduction—unlocked through electrochemically coupled oxygen-atom transfer.
⚙️ Carbon-supported Fe nanoparticles play a double role: oxygen-transfer catalyst + conversion-type cathode material.
⚡ >50% LiClO₄ conversion
⚡ 1,150 mAh g⁻¹ capacity
⚡ 1,950 Wh kg⁻¹ (per kg of LiClO₄)
It is a proof of concept—not yet a practical battery—but it opens a new route toward harvesting the largely unexplored energy of p-block oxoanions.
Much inspired by discussions with Prof. Reinhard Nesper (ETH emeritus) over a decade ago.
pubs.acs.org/doi/10.1021/ja…
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