@furoppi_chem Exciting new mechanism reported in JACS — difluorocarbene acts as both a fluorocarbanion and a fluorocarbon radical precursor, expanding the scope of fluorinated molecule synthesis! #CatalyticCoupling#Organofluorine
NEW Pd-cat. mechanism converts difluorocarbene into difluoroalkyl radicals via Pd–CF₂ species|Unlocking Difluorocarbene as a Fluorocarbanion and a Fluorocarbon Radical Precursor for Sequential Catalytic Coupling
pubs.acs.org/doi/10.1021/ja…
Happy to share our latest work in Org. Lett. 🚀
We report a cationic cascade trailing into a Piancatelli rearrangement, enabling access to skeletally diverse polycyclic frameworks using HFIP as the sole promoter.
Read here 👉 doi.org/10.1021/acs.or…@JOC_OL
Excited to share our latest publication: 1,1,1,3,3,3-Hexafluoroisopropanol-Promoted Synthesis of Structurally Diverse Alkylidene-4-thiazolidinones/selenazolidinones Involving an Azaoxyallyl Cation | Organic Letters pubs.acs.org/doi/10.1021/ac…@JOC_OL@SUBHADEEPHAZR12@ManveerP16150