Ashish

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Ashish

Ashish

@Parihar_chemist

PhD Candidate at @RutgersChem Organometallics and Catalysis @Goldman_Group MS (Chemistry) @IITKanpur

Piscataway, NJ Katılım Eylül 2015
281 Takip Edilen202 Takipçiler
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Ashish
Ashish@Parihar_chemist·
Check this preprint which covers a big chunk of my doctoral work here at @Goldman_Group . A big thanks to Faraj, @alansgoldman for completing this story. And a huge shoutout to @iridium_tea for fruitful discussions on cationic pincer iridium chemistry.
Goldman Group@Goldman_Group

🚨Check out this new preprint go.shr.lc/4f6mlGG by @Parihar_chemist of @Goldman_Group at @RutgersChem reporting (iPrPCP)IrH+ for dehydrogenation, hydrogenation & H/D exchange with unusual selectivity. Proceeding via a novel mechanism of C-H addition & beta-H elimination.

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Ashish
Ashish@Parihar_chemist·
I am thrilled to share that the final version of our work is now published in @ACSPublications JACS Au doi.org/10.1021/jacsau… @Goldman_Group @RutgersChem
Ashish@Parihar_chemist

🚨Check out this preprint from @Goldman_Group on (Pybox)Os-catalyzed tail-to-tail homo/hetero coupling of α-olefins. Striking mechanistic differences from isoelectronic (Phebox)Ir shed light on fundamental oxidative addition/reductive elimination steps. go.shr.lc/4mW0XaY

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Ashish
Ashish@Parihar_chemist·
🚨Check out this preprint from @Goldman_Group on (Pybox)Os-catalyzed tail-to-tail homo/hetero coupling of α-olefins. Striking mechanistic differences from isoelectronic (Phebox)Ir shed light on fundamental oxidative addition/reductive elimination steps. go.shr.lc/4mW0XaY
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Alan Goldman
Alan Goldman@alansgoldman·
Proud of this work with collaborator (and former group member) Santanu Malakar @random_chemist, lead author Souvik Mandal @souvik_mndl, and team including Samuel Zhou, Rachel Allen, Faraj Hasanayn, Alex Miller, Quinton Bruch - see paper for all authors...!
Chemical Science@ChemicalScience

By investigating the reduction of dinitrogen to ammonia with a pincer-Mo complex, Santanu Malakar, Alan Goldman and colleagues provide new insights into nitride-to-ammonia conversion. Read for free, here: doi.org/10.1039/D5SC00…

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Nitin sharma
Nitin sharma@nitinsharma_07·
Excited to see our work featured here! Our latest total synthesis has just been accepted in Angewandte Chemie @angew_chem Greatful to Prof. Dethe @Dethe_IITKanpur for his constant guidance and support, and to Sakshi @sakshijuyal_14 for her valuable contribution. @Chemistry_IITK
Total Synthesis@TotalSynthesis

Concise Enantioselective #TotalSyntheses of Rearranged ent-Trachylobane Diterpenoids (–)-Wallichanols A and B by Dattatraya H. Dethe, Nitin Sharma, and Sakshi Juyal in @angew_chem onlinelibrary.wiley.com/doi/10.1002/an…

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Alan Goldman
Alan Goldman@alansgoldman·
@Goldman_Group @Parihar_chemist @RutgersChem Several bizarre aspects of this system include a huge preference for both dehydrogenation AND hydrogenation of 5, 7 and 8 membered rings vs. 6-membered. Much gratitude (and possible co-authorship?) to any organic-savvy chemist who can find a good application for this selectivity!
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Alan Goldman
Alan Goldman@alansgoldman·
Kudos to @Parihar_chemist for an awesome study revealing a novel mode of C-H activation/ dehydrogenation/hydrogenation by a protonated pincer Ir catalyst
Goldman Group@Goldman_Group

🚨Check out this new preprint go.shr.lc/4f6mlGG by @Parihar_chemist of @Goldman_Group at @RutgersChem reporting (iPrPCP)IrH+ for dehydrogenation, hydrogenation & H/D exchange with unusual selectivity. Proceeding via a novel mechanism of C-H addition & beta-H elimination.

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Ashish
Ashish@Parihar_chemist·
Congratulations to my mentor of grad school @random_chemist who will be starting as an Assistant Professor. He introduced me to the field of organometallic chemistry (experimental and computational). PS: His students will be lucky to have a guide like him.
Goldberg Lab@GoldbergLabPenn

Celebrated our postdoc @random_chemist Santanu's last day with a chinatown lunch and boba 🧋 outing! Santanu has accepted a position as an Assistant Professor at Rutgers University-Camden Congratulations Santanu!!! #summer2024

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Belvin Thomas
Belvin Thomas@ThomasBelvin·
Excited to share a new paper published in @JMaterChem where we show that Bismuth can enhance the electrocatalytic activity of Cobalt oxide towards acidic oxygen evolution reaction (OER) and Bismuth can also serve as an active site. doi.org/10.1039/D4TA02…
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Goldman Group
Goldman Group@Goldman_Group·
@Goldman_Group lab members at this years GRC Organometallics in Rhode Island.
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Rick Remsing
Rick Remsing@rcremsing·
New preprint from @atulCthakur on another Titan cryomineral in a plastic phase Weak interactions = nearly free rotation and disorder persisting to very low temperatures arxiv.org/abs/2405.17751
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Vishav Sharma
Vishav Sharma@vishavsharma_·
Thiamin Biosynthesis!! Radical SAM Enzyme!! Remarkably Complex Chemistry!! Check out our work on the mechanistic enzymology of the ThiC-catalyzed reaction in bacterial thiamin biosynthesis in @ACSCentSci. It was a great team effort. (1/3) pubs.acs.org/doi/10.1021/ac…
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Keşfet

@ACSPublications @Goldman_Group @RutgersChem @souvik_mndl @nitinsharma_07 @angew_chem @Dethe_IITKanpur @sakshijuyal_14