TiefenbacherLab

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TiefenbacherLab

TiefenbacherLab

@TiefenbacherLab

Student-run account for the Tiefenbacher group

Basel, Switzerland Katılım Ekim 2016
162 Takip Edilen686 Takipçiler
TiefenbacherLab
TiefenbacherLab@TiefenbacherLab·
Our latest research is now published in JACS Au! 🎉We've developed a novel macrocycle that self-assembles into a catalytically active hexameric cage, capable of converting substrates too large for traditional resorcin[4]arene capsules pubs.acs.org/doi/10.1021/ja…
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TiefenbacherLab
TiefenbacherLab@TiefenbacherLab·
We report a computational algorithm capable of predicting the outcome of complex carbocationic rearrangements, and employ it to encode complex terpene structures into much simpler precursors. Great collaboration with the Grzybowski and Burke groups @Nature nature.com/articles/s4158…
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TiefenbacherLab
TiefenbacherLab@TiefenbacherLab·
We report highly β-selective furanosylation reactions enabled by the resorcin[4]arene capsule. In contrast to pyranosylation inside the same catalyst, the furanosylation mechanism is shifted towards SN1 on the continuum between SN1-SN2 substitution types. pubs.acs.org/doi/full/10.10…
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TiefenbacherLab
TiefenbacherLab@TiefenbacherLab·
Our recent work on the unusually large, conformationally restricted acridane[4]arenes and their application to megalo-cavitands made it to the ACS C&EN’s molecules of the year vote! Congratulations to Jonathan for his great work. cen.acs.org/synthesis/Chec…
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The Matile Group
The Matile Group@matile_group·
Hyperresponsive expanding XL product space? Well then, never mind, @NCCR_MSE spirit at its best, amazing how these magic @TiefenbacherLab capsules make new molecules, how pnictogen-bonding catalysis breaks the Baldwin rules. Thank you @ChemicalScience @UNIGEnews @sciences_UNIGE
UniGE - Organic Chemistry Department@UniGe_OrgChem

New contribution from the Matile and Viger-Gravel groups @matile_group @JazViger in Chem. Sci.: "Decoded fingerprints of hyperresponsive, expanding product space: polyether cascade cyclizations as tools to elucidate supramolecular catalysis" doi.org/10.1039/D2SC03…

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J Org Chem/Org Lett
J Org Chem/Org Lett@JOC_OL·
Thioderivatives of Resorcin[4]arene and Pyrogallol[4]arene: Are Thiols Tolerated in the Self-Assembly Process? A study in #OL on the influence of free thiols on self-assembly, disulfide chemistry, and catalysis. From @TiefenbacherLab. Check it out: fal.cn/3hIQd
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The Matile Group
The Matile Group@matile_group·
Supramolecular catalysts (capsules, anion-π, …) compared for asymmetric autocatalysis, self-replication, and breaking of the Baldwin rules – @NCCR_MSE teamwork makes it possible @TiefenbacherLab @UNIGEnews @sciences_UNIGE @NCCR_ChemBio
The Matile Group tweet media
UniGE - Organic Chemistry Department@UniGe_OrgChem

New contribution from the Mazet and Matile (@matile_group) groups in Chem. Eur. J.: "Bioinspired Ether Cyclizations within a π-Basic Capsule Compared to Autocatalysis on π-Acidic Surfaces and Pnictogen-Bonding Catalysts" doi.org/10.1002/chem.2…

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