@Young__Chem I still remember finding you in the lab at 1 am sometime in Fall 2021 having just figured out what the hell was going on in the VT NMR data and drawing what ended up being the graphical abstract on your whiteboard…
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Arun Sridharan
183 posts
Arun Sridharan
@borntoarun
Industry chemist, teacher, climber, runner, outdoors enthusiast. NJ native (youse) living in TX (y’all). Occasional retweets of @dog_feelings.
Katılım Eylül 2020
322 Takip Edilen227 Takipçiler
Back in 2020, soon after I had isolated the Fe-S cluster terminal imido complex, Dan remarked “I wonder what happens if you oxidize it.” Five years later, we finally have the answer: pubs.acs.org/doi/10.1021/ja…
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Arun Sridharan retweetledi
Nitrogen Subvalency in a Four-Member Redox Series of Iron–Sulfur Cluster Imido Complexes | Journal of the American Chemical Society @ChemistryMIT @MIT pubs.acs.org/doi/10.1021/ja…
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This work has been five years in the making - we first collected the Mössbauer spectrum of the imido cation in Oct 2020 - and I am so happy to finally share this with the community!
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These findings are interfaced to CASSCF and BS DFT calculations, in addition to sc-XRD and Mössbauer, which all point to redox events significantly delocalized onto the FeNAr unit.
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Arun Sridharan retweetledi
I am thrilled to share that I will start my independent career as an assistant professor @VanderbiltChem this August! Special thanks to Profs. Daniel Suess, Jeffrey Long, and Alexander Radosevich. My lab will integrate inorganic synthesis and electronic structure studies!
Vanderbilt Chemistry@VanderbiltChem
Mengshan Ye joins the faculty for the upcoming 25-26 academic calendar year continuing her bioinorganic and physical inorganic research at Vanderbilt University. Swipe to read more about Dr. Ye, her research and what she is most excited about as she makes her move to Vanderbilt.
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Arun Sridharan retweetledi
We're delighted to announce that our synthesis of mobiustrine A has been published in Orgasmic Letters! @radscientist_
PDF: jabde.com/wp-content/upl…
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Arun Sridharan retweetledi
Really excited to share this work! Phosphorous is the new cool atom! pubs.acs.org/doi/10.1021/ja…
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Arun Sridharan retweetledi
🔥Hot🔥 nitridos in your area 👀! Read about our open-shell Fe(IV) nitrido in JACS and congratulations to our graduate student Jeewhan!
pubs.acs.org/doi/10.1021/ja…
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Arun Sridharan retweetledi
Activation of Strong π–Acids at [Fe4S4]+ Clusters Enabled by a Noncanonical Electronic Structure | Journal of the American Chemical Society @MIT @ChemistryMIT #Activation #Strong #Pi #Acids #Fe #Clusters #Noncanonical #Electronic #Structure pubs.acs.org/doi/10.1021/ja…
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Arun Sridharan retweetledi
Congratulations to @lwarring1994 on a successful PhD defense @ChemistryMIT and excellent work on antimony and bismuth carbone and arene chemistry!
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Arun Sridharan retweetledi
What's going on between Copper and Carbon 👀👀👀?...read all about it in our newest paper: "C–H Insertion from Isolable Copper Benzylidenes" and congratulations to our graduate student Erika Amemiya on an awesome paper!
pubs.acs.org/doi/10.1021/ja…
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Congrats Jessica! Nice use of simple reagents to address an important problem in testing water for NDMA.
One interesting side point we found from the Mössbauer data - the oxidation state of commercial Naphthol Green B dye is likely Fe2+, not Fe3+ as is commonly reported!
Swager Group@SwagerGroup
Take a look at our latest @ACS_Sensors publication on NDMA detection in water, led by former grad student @jesscbeard and postdoc @ChiHsienWang. A big step towards rapid, affordable environmental sensing! pubs.acs.org/doi/10.1021/ac…
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Part II of the McSkimming lab’s high-spin metal hydride chemistry, this time at Fe2+, made using an under-used hydride reagent! Mössbauer + DFT too:
pubs.acs.org/doi/10.1021/ac…
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Congrats again Dan, this is awesome!
Miramodus@Miramodus
Fe-S clusters exist in a wide range of proteins including Nitrogenase and Ferredoxins . We've recently completed a set of Fe-S cluster models on oak bases for a newly-tenured researcher @ChemistryMIT. Impressive collection when it was all together! miramodus.com/molecular-mode…
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Arun Sridharan retweetledi
On Thursday morning I was telling my students that the structure of MAO remains a challenge despite decades of research. A few hours later I learned that this has changed. Check out the work from ExxonMobil @ScienceMagazine
science.org/doi/10.1126/sc…
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A rare example of a high-spin metal hydride complex, with full characterization by EPR, and a nice analogy drawn between Mn2+ and Fe3+. Lots of cool new chemistry being realized on the NNC heteroscorpionate platform. Congrats!
J. Am. Chem. Soc.@J_A_C_S
Terminal Hydride Complex of High-Spin Mn | Journal of the American Chemical Society @Tulane @TulaneChem @NorthwesternU @NUChemistry #Hydride #Mn #HighSpin #Complex #Coordination #Inorganic pubs.acs.org/doi/10.1021/ja…
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Excited to share a new paper from my colleagues at Exxon Organometallic Catalysis: they solved the crystal structure of methylaluminoxane, a 40-year unsolved problem in the field of olefin polymerization catalyst activation: science.org/doi/10.1126/sc…
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