Shengyang Ni

From Boron to Bismuth: The Pre-transmetalation Complex in the Aryl Transfer | Journal of the American Chemical Society pubs.acs.org/doi/10.1021/ja…

Bismuth-photocatalysed Heck-type coupling with alkyl and aryl electrophiles bit.ly/3LewRl6

Accessing transient Bi(II) for catalytic XAT. Applied in the context of Heck-type reactions. Another tile in the reactivity floor of bismuth.

🚨Calling medicinal chemists🚨: A Suzuki het-het coupling sometimes does not require complex ligands. An air stable Ni would do. Amazing work from @rsaeb2 Rakan Saeb and Byeongdo Roh. onlinelibrary.wiley.com/doi/10.1002/an…

Expanding the horizons for bismuth as a redox catalyst. Now for cyclopropanation. @J_A_C_S pubs.acs.org/doi/epdf/10.10… with @ShengyangN & @DavideSpinnato2

Thianthrene meets nickel catalysis! We are happy to present our newest publication in @NatureCatalysis about C–heteroatom coupling of TT-salts with electron-rich aryls using nickel and light. Great collaboration with @CornellaLab doi.org/10.1038/s41929…

Happy to share this work from my postdoc in @CornellaLab (w/ Feng, @uri_planas, @MrIrieman, @Nils_Not, Kalishankar, Alex)! We demonstrate mechanistic studies on Bi-catalyzed transfer hydrogenation via Bi(I)/Bi(III) redox cycling. onlinelibrary.wiley.com/doi/10.1002/an…

Oxidative Addition of Aryl Electrophiles into a Red-Light-Active Bismuthinidene | Journal of the American Chemical Society @CornellaLab @maxplanckpress @TotalSyntheses #OxidativeAddition #AreneElectrophiles #RedLIght #Bismuthinidene pubs.acs.org/doi/10.1021/ja…

Nickel meets Aryl TTs! Check out our most recent publication in @J_A_C_S, a great collaboration with @CornellaLab about Ni(I)-Catalyzed Halogenation of Arenes. Congrats to all involved! pubs.acs.org/doi/10.1021/ja…

Nickel Meets Aryl Thianthrenium Salts: Ni(I)-Catalyzed Halogenation of Arenes @maxplanckpress @ritter_lab @CornellaLab @TotalSyntheses #Ni #Arenes #Thianthrenium #Catalysis #Arylhalides #Halogenation pubs.acs.org/doi/10.1021/ja…

@LIChunXiaoElia1 多谢师兄哇🥳🥳🥳

Congratulations, 昇陽@ShengyangN

@Zibo_White Thanks🥳🤣👻

Congratulations 🎉 @ShengyangN

@FranckF1476 @J_A_C_S @CornellaLab Thanks a lot, Franck! I couldn’t have achieved it without your help🥳🥳🥳

How does the reductive elimination of aryl-F from Bi(V) work?🤔 Check out my last dance with @CornellaLab, a HUGE study that includes kinetics, DFT, 23 (!) X-ray structures and improved stoichiometric and catalytic methodologies to furnish fluoroarenes! pubs.acs.org/doi/10.1021/ja…

Catalytic synthesis of phenols with N2O. An enormous effort spearheaded by @FranckF1476 !Congrats to all the authors involved. nature.com/articles/s4158…

The lab was honored to play a very tiny role in this story with #Pfizerchemistry as radical-based decarboxylative amino acid synthesis was used to optimize Paxlovid.