Yunyan Sun

169 posts

Yunyan Sun

Yunyan Sun

@YunyanSun

Assistant Professor @ECNUer; Working at the interface of bio/organic/polymer. Interested in molecular design and its applications in bio/organic materials.

Katılım Eylül 2018
383 Takip Edilen330 Takipçiler
Kelsie Wentz
Kelsie Wentz@kek_kelsie·
I'm thrilled to share that I will be starting my independent career @IUBChemistry in July! The Wentz lab will interface synthetic chemistry with materials science, while providing strategies to access new generations of molecular building blocks and macromolecular materials.
Kelsie Wentz tweet media
English
36
14
211
27.6K
Yunyan Sun retweetledi
Baran Lab
Baran Lab@BaranLabReads·
🚨RADICAL RETHINK: STEREORETENTIVE CROSS COUPLING UNLOCKED🚨 Today in @ChemRxiv (chemrxiv.org/engage/chemrxi…) the first method for stereoretentive radical cross-coupling is disclosed. No fancy ligands or redox needed—just a Ni-diazene twist. 120 years after Gomberg, a new chapter begins. Quick summary: Since Gomberg discovered free radicals over 120 years ago and Kochi pioneered radical cross-coupling in the 1970s, this field has surged with interest for linking C(sp3) fragments. Unlike traditional polar methods (e.g., Suzuki), radical cross-coupling excels with saturated systems, offering mild conditions and chemoselectivity to build complex molecules from common fragments. Until now, enantiospecific radical cross-coupling was deemed impossible due to rapid racemization, but today that changes with readily available sulfonylhydrazides and a simple Ni-catalyst. This stereoretentive approach, enabled by a unique Ni-diazene transition state and driven by loss of N2, skips chiral ligands and redox steps, opening new possibilities for synthesis.
Baran Lab tweet media
English
17
169
646
197K
Ilia Kevlishvili
Ilia Kevlishvili@KevlishviliIlia·
I'm very excited to share that I will start my independent career as an Assistant Professor @BaylorCBC starting August 2025! My team will integrate computational chemistry, cheminformatics, and machine learning to innovate in catalysis and materials!
English
10
2
56
7K
Yu Zheng
Yu Zheng@yuzhengstanford·
Thrilled to share my postdoc work is online in ⁦@J_A_C_S⁩ . We used a rheo-fluorescence set up to directly see and quantify bond breakage events when associative polymer undergoes large shear deformation. Thanks to my advisor ⁦and all coauthors! pubs.acs.org/doi/10.1021/ja…
English
3
8
84
8.3K
Yunyan Sun
Yunyan Sun@YunyanSun·
Check out my last piece of work in my PhD with @Mechanophore! We developed a “cartoon picture” ( a triangle!) to make sense of mechanochemistry under tension. Special thanks to all the reviewers who helped to greatly improved the manuscript! doi.org/10.1021/jacs.4….
English
3
5
30
2.3K
Yunyan Sun
Yunyan Sun@YunyanSun·
@Mechanophore @CciMonet Beyond the fundamental insights in the paper, here is one figure I think can be helpful practically (suggested by one kind reviewer!) It tells us the “privileged handles” we should use to incorporate mechanophores.
Yunyan Sun tweet media
English
0
0
4
663
Yunyan Sun
Yunyan Sun@YunyanSun·
Many thanks to Jeff who has contributed a ton to this paper! Please make sure to check out the interactive python tool developed by @Mechanophore in the SI!!! Also thank Fangbai who helped to conduct a few simulations. Also thanks the support from @CciMonet
English
1
0
3
340
Yunyan Sun retweetledi
The Nobel Prize
The Nobel Prize@NobelPrize·
BREAKING NEWS The Royal Swedish Academy of Sciences has decided to award the 2024 #NobelPrize in Chemistry with one half to David Baker “for computational protein design” and the other half jointly to Demis Hassabis and John M. Jumper “for protein structure prediction.”
The Nobel Prize tweet media
English
510
8.4K
19.3K
9.1M
Shixuan Wei
Shixuan Wei@shixuanwei_chem·
For me it is always fun to work on some fluorescent materials and it is amazing to see that colorful emission can be achieved by mechanophores. Congratulations to the MONET team!
Yunyan Sun@YunyanSun

Please check out our work @J_A_C_S on Multicolor and White Emission from Mechanically Caged AIEgens. pubs.acs.org/doi/10.1021/ja… I am glad it is also selected as the ACS Editor’s Choice! This work was done with a phenomenal undergrad @CHEM_Kecheng who will apply for grad school soon

English
1
0
5
396
Yunyan Sun
Yunyan Sun@YunyanSun·
Please check out our work @J_A_C_S on Multicolor and White Emission from Mechanically Caged AIEgens. pubs.acs.org/doi/10.1021/ja… I am glad it is also selected as the ACS Editor’s Choice! This work was done with a phenomenal undergrad @CHEM_Kecheng who will apply for grad school soon
English
10
14
114
18.5K