Pablo Gabriel
45 posts
English
Out now in @J_A_C_S - 1,2-Redox Transpositions of Tertiary Amides
We combine Ir-catalysed reduction of amides with enamine functionalization to bring about 1,2-carbonyl transpositions and more.
Congrats to the team - @benshennan11, Sergio & Gabriele!
pubs.acs.org/doi/10.1021/ja…
English
Pablo Gabriel retweetledi
Great to see this out now!
Here we present a convenient route to (hopefully) useful beta-functionalized amines directly from tertiary amides.
Thanks to Sergio and Gabriele for all your help along the journey!
Dixon Group@dixon_group
Out now in @J_A_C_S - 1,2-Redox Transpositions of Tertiary Amides We combine Ir-catalysed reduction of amides with enamine functionalization to bring about 1,2-carbonyl transpositions and more. Congrats to the team - @benshennan11, Sergio & Gabriele! pubs.acs.org/doi/10.1021/ja…
English
Congratulations to Molly, who defended her PhD yesterday and became Dr Fairchild!
English
Pablo Gabriel retweetledi
We're thrilled to announce that our enantioselective desymmetrization of phosphorus (V) is now out in Nature Chemistry! 🔥
Congratulations to @formica_michele and the team @tanya_rogova, Yao, Naoto, Bran, @FarleyAlistair @fjduarteg @KenYamazaki5
🎉🎉
nature.com/articles/s4155…
English
Pablo Gabriel retweetledi
Redox Transpositions of Tertiary Amides - now online at ChemRxiv!
Oxidation states dance in our new reductive activation of amides to enable one-pot synthesis of beta-functionalized amines.
Congratulations to @benshennan11 and Sergio!
chemrxiv.org/engage/chemrxi…
English
@compoundchem Nice graphics as usual!
You might want to change the description for Irma Goldberg though, since Marta Catellani's discovered the eponymous reaction over 25 years ago now!
English
Pablo Gabriel retweetledi
Massive congrats to Roman, Sam, and the team for their enantioselective total synthesis of himalensine A! 🎉
A new cyclization reaction enables efficient, enantioselective construction of the core - modelled by @KenYamazaki5 and @TrevorAHamlin.
pubs.acs.org/doi/10.1021/ja…
English
Pablo Gabriel retweetledi
I'm very happy to share our latest work, published now in @ChemRxiv, the BIMP-catalysed enantioselective nitroalkane addition to unactivated α,β-unsaturated esters!
Congrats to @FarleyAlistair and Iain McLauchlan!
@OxfordSynthesis @dixon_group
chemrxiv.org/engage/chemrxi…
English
Pablo Gabriel retweetledi
BREAKING NEWS:
The Royal Swedish Academy of Sciences has decided to award the 2022 #NobelPrize in Chemistry to Carolyn R. Bertozzi, Morten Meldal and K. Barry Sharpless “for the development of click chemistry and bioorthogonal chemistry.”
English
Pablo Gabriel retweetledi
Branching out: redox strategies towards the synthesis of acyclic α-tertiary ethers – our latest review out now in @ChemSocRev!
A massive collaborative effort by members of the @OxfordSynthesis SBM CDT 2020 Cohort and our own @benshennan11. Well done all!
doi.org/10.1039/D1CS00…
English
@GusTheChemist @OceAlaB What do you think is worse @GusTheChemist , the awkward alkene, the terminal C3H groups, the lack of perspective in the key structural motif?
English
Pablo Gabriel retweetledi
Difluoroalkylation of Tertiary Amides and Lactams by an Iridium-Catalyzed Reductive Reformatsky Reaction – out now in Org Lett! @JOC_OL
Congratulations to @PBiallas and @KenYamazaki5 🔥
pubs.acs.org/doi/10.1021/ac…
English
@r6vT6hSx6jdB2xP @J_A_C_S @dixon_group @TrevorAHamlin @VU_TheoCheM Congrats Shinya! Still remember the day you arrived in the group and we celebrated Yao’s natural product at the pub! Now it’s your turn!
English
Hi guys, thank you very much. It was tough but we've done it. Congrats to all! 🤗
The total synthesis of madangamine E is out now in @J_A_C_S
✌︎('ω')✌︎✌︎('ω')✌︎✌︎('ω')✌︎
@dixon_group @TrevorAHamlin @VU_TheoCheM #compchem
Dixon Group@dixon_group
Great to see our total synthesis of madangamine E is out now in @J_A_C_S and #openaccess! Congratulations to Shinya (@r6vT6hSx6jdB2xP), @benshennan11, @KenYamazaki5, Angel, Vasu and of course a great #compchem collaboration with @TrevorAHamlin!🔥 pubs.acs.org/doi/10.1021/ja…
English
@KenYamazaki5 @r6vT6hSx6jdB2xP @benshennan11 @J_A_C_S @dixon_group @TrevorAHamlin @VU_TheoCheM There goes your paper of the week Ken, published on a Monday! So that leaves you up to 13 free days before the next one, enjoy the break!
English
Fantastic to see the work from @r6vT6hSx6jdB2xP and @benshennan11 on the total synthesis of madangamine E out now in @J_A_C_S 👏
Great to be a part of the team!🥂
@dixon_group @TrevorAHamlin @VU_TheoCheM #compchem
pubs.acs.org/doi/10.1021/ja…
English
Pablo Gabriel retweetledi
Really pleased to see our desymmetrization approach to madangamine E now out in @J_A_C_S!! 🎉🥳
It's been an honour to be a part of the team and work on this #totalsynthesis with Shinya @r6vT6hSx6jdB2xP and @KenYamazaki5!
Dixon Group@dixon_group
Great to see our total synthesis of madangamine E is out now in @J_A_C_S and #openaccess! Congratulations to Shinya (@r6vT6hSx6jdB2xP), @benshennan11, @KenYamazaki5, Angel, Vasu and of course a great #compchem collaboration with @TrevorAHamlin!🔥 pubs.acs.org/doi/10.1021/ja…
English
@KenYamazaki5 @ACSCatalysis @osaka_univ_e Congrats Ken!
I can’t remember the last week you didn’t publish a paper!!
おめでとう！
日本語
Check out our recent work on site-selective Pd-catalyzed C-H activation just published in @ACSCatalysis!🔥
Congrats to Qiyuan in Chatani group for his huge amount of work🥂
@osaka_univ_e #compchem
pubs.acs.org/doi/10.1021/ac…
English
@GusTheChemist Super dark for me as well.
You can buy in different mesh I believe, of course the finer is supposed to be more active!
English
Pablo Gabriel retweetledi
Difluoroalkylation of tertiary amides and lactams by an iridium-catalyzed reductive Reformatsky reaction out now on @ChemRxiv!
Congratulations to Phillip and @KenYamazaki5!
doi.org/10.33774/chemr…
English
Pablo Gabriel retweetledi
Great work by Dan, @tanya_rogova and collaborators @dixon_group!
Dixon Group@dixon_group
A Three-Component Ugi-Type Reaction of N-Carbamoyl Imines Enables a Broad Scope Primary α-Amino 1,3,4-Oxadiazole Synthesis, out now in @JOC_OL! Congrats to Dan MR, Lizzie and @tanya_rogova! pubs.acs.org/doi/10.1021/ac…
English