Dilman Lab

Pyridine meets difluorocarbene. Our paper on synthesis of difluoroalkylated hetarenes is finally online! Please check it out in @JOC_OL #fluorine #carbene #heterocycles bit.ly/3Bg0fx3

Just accepted Update by Alexander D. Dilman and co-authors: Generation of Alkyl #Radicals from #Thiols via #Zinc Thiolates: Application for the Synthesis of gem‐Difluorostyrenes onlinelibrary.wiley.com/doi/abs/10.100…

Just accepted Update by Alexander D. Dilman and co-authors: #Photoredox #Fluoroalkylation of #Hydrazones in Neutral and #Reductive Modes onlinelibrary.wiley.com/doi/abs/10.100…

Visible-light-promoted reversible sulfide/iodide exchange in fluoroalkyl sulfides enabled by electron donor-acceptor complex formation (van der Worp, Kosobokov, Dilman @DilmanLab) onlinelibrary.wiley.com/doi/10.1002/cp…

After having thought about the dehydoxylative cross-coupling for years (since I was a postdoc in Baran Lab @BaranLabReads), we finally figured out an expedient method @J_A_C_S: pubs.acs.org/doi/10.1021/ja…

Using the Thiyl Radical for Aliphatic Hydrogen-Atom Transfer: Thiolation of Unactivated C-H Bonds by @DilmanLab onlinelibrary.wiley.com/doi/10.1002/an…

@andrei_yudin @A_Aspuru_Guzik @SeferosGroup Great work, Andrei! Novel structures, and readily accessible!

Boramidines are new motifs with potential in many areas. Finding small heterocycles that are stable to water and a wide range of solvents, yet have somehow eluded synthesis, is interesting. @A_Aspuru_Guzik @SeferosGroup pubs.acs.org/doi/10.1021/ja…

Photoredox-catalyzed silyldifluoromethylation of silyl enol ethers @DilmanLab @BeilsteinInst: doi.org/10.3762/bjoc.1…

ortho-Dialkylamino Arylboranes as Efficient Reagents for Difluorocarbene Trapping : pubs.rsc.org/en/content/art…

Trapping of Difluorocarbene by Frustrated Lewis Pairs (Dilman) doi.wiley.com/10.1002/anie.2…

Thank you for highlighting our work.

Acetylene trimerization reported by Berthelot and Zelinsky was finally unveiled. The mistery of self-promoted carbocatalytic synthesis of benzene. @AnanikovLab acspubs.co/Npvk30qhLwM

Double (vicinal) C-H functionalization of alcohols! Check out this cool “reversed” radical/polar crossover mechanism @J_A_C_S by Allen, Raymond, & Ethan! pubs.acs.org/doi/10.1021/ja…

Our latest paper "Visible-Light-Promoted Iododifluoromethylation of Alkenes via (Phosphonio)difluoromethyl Radical Cation" is now online @JOC_OL #visiblelight #catalysis #radicals pubs.acs.org/doi/10.1021/ac…

Seeing double👀👀 after new year's revelry🎆? Then please check out our latest publication on dual Cr-photoredox catalysis to access 1,2-amino alcohols, just accepted in @J_A_C_S. #chromium #photoredox #catalysis #aminoalcohols pubs.acs.org/doi/10.1021/ja…

Check out our recent @JOC_OL paper. pubs.acs.org/doi/abs/10.102… #photoredox #radical #fluorine

Ni(Fstb)3. An air-stable source of Ni(0). Thinking outside the (Glove)box. @LNattmann @rsaeb2 nature.com/articles/s4192…

Check out our new paper – now published in @ChemicalScience ! pubs.rsc.org/en/content/art… #photoredox #radical #fluorine

Photoredox Catalytic alpha-Alkoxypentafluorosulfanylation of alpha-methyl- and alpha-phenylstyrene using SF6 (Wagenknecht) doi.wiley.com/10.1002/anie.2…